Valiano produces wines from Chianti, the heart of Tuscany's classical wine country. The winery's portfolio centers on the region's traditional expressions: Sangiovese-based Chianti Classico Gran Selezioni, including San Lazzaro, which showcases the variety's characteristic structure and earthy depth. The estate also works with Cabernet Franc, evident in Pècchero, a wine that demonstrates the potential of this variety in the Tuscan context. A third flagship, 6.38 Chianti Classico Gran Selezione, blends Sangiovese with Merlot and Cabernet Sauvignon, reflecting the modern Tuscan approach to Chianti production. Wines from Valiano have been assessed by Wine Enthusiast, Wine Spectator, Decanter, and Wine Advocate.